Phthalate Reference Standards

Phthalate Standards


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Also known as plasticizers, Phthalates are a class of chemical compounds that are generally used as an additive to improve flexibility and durability in plastic. They are also widely applied in cosmetic and personal care consumer products such as hair spray, nail polish and fragrances. Prolonged exposure to phthalates has been linked to a series of adverse health effects in human such as cancer, endocrine disruptions, and reduced fertility.
Regulatory bodies such as the US Food and Drug Administration (USFDA) and the European Chemicals Agency (ECHA) are regularly updating their lists of phthalates banned from use in consumer products.

The Consumer Products Safety Commission (CPSC) has proposed banning the use of several phthalates in materials for children’s toys. In 2008, a congressional edict banned dibutyl, n-butyl benzyl and di-2-ethylhexyl (DEHP) phthalates as potential health risks. Diisononyl (DINP), di-n-octyl (DNOP) and diisodecyl (DIDP) phthalates also were banned on an interim basis. CPSC’s advisory panel now recommends a permanent ban on DINP, but says the ban on DNOP and DIDP should be lifted. In addition, the panel is considering a ban on diisobutyl, di-n-pentyl, di-n-hexyl and dicyclohexyl phthalates.

Phthalates

  1. Benzyl butyl phthalate
    Neat
  2. Benzyl butyl phthalate (BBP)
    100 µg/mL in MeOH
    Single
  3. bis(2-Ethylhexyl) phthalate (DEHP)
    Neat
  4. bis(2-Ethylhexyl) phthalate (DEHP)
    100 µg/mL in Methanol
    Single
  5. Diamyl phthalate
    Neat
  6. Diamyl phthalate (DPNP)
    100 µg/mL in MeOH
    Single
  7. Dicyclohexyl phthalate (DCHP)
    100 µg/mL in MeOH
    Single
  8. Dihexyl phthalate
    Neat
  9. Dihexyl phthalate (DHP)
    100 µg/mL in MeOH
    Single
  10. bis(2-Ethylhexyl)phthalate (DEHP)
    1000 µg/mL in Methanol
    Single
  11. Di-n-butyl phthalate
    100 µg/mL in MeOH
    Single
  12. Di-n-butyl phthalate
    1000 µg/mL in MeOH
    Single
  13. Diethyl phthalate
    100 µg/mL in Methanol
    Single
  14. Diethyl phthalate
    1000 µg/mL in Methanol
    Single
  15. Dimethyl phthalate
    100 µg/mL in MeOH
    Single
  16. Dimethyl phthalate
    1000 µg/mL in Methanol
    Single
  17. Di-n-octyl phthalate (DNOP)
    100 µg/mL in MeOH
    Single
  18. Benzyl butyl phthalate
    5.0 mg/mL in MeOH
    Single
  19. Di-n-butyl phthalate
    5.0 mg/mL in MeOH
    Single
  20. Di-n-octyl phthalate
    5.0 mg/mL in MeOH
    Single
  21. Diethyl Phthalate
    5.0 mg/mL in MeOH
    Single
  22. Dimethyl phthalate
    5.0 mg/mL in MeOH
    Single
  23. Dicyclohexyl phthalate
    1000 µg/mL in Acetonitrile
    Single
  24. Diallyl phthalate
    Neat
  25. Dibutyl phthalate
    Neat
  26. Dicyclohexyl phthalate
    Neat
  27. Diethyl phthalate
    Neat
  28. Dimethyl phthalate
    Neat
  29. Di-n-octyl phthalate (DNOP)
    Neat
  30. Diphenyl phthalate
    Neat
  31. Dibenzyl phthalate
    Neat
  32. bis(2-Methoxyethyl) phthalate
    Neat
  33. bis(4-Methyl-2-pentyl) phthalate
    Neat
  34. bis(2-Ethoxyethyl) phthalate
    Neat
  35. bis(2-n-butoxyethyl) phthalate (DBEP)
    Neat
  36. Diisobutyl phthalate (DIBP)
    Neat
  37. 2-Butoxy-2-oxoethyl butyl phthalate
    Neat
  38. Diisopentyl phthalate (DIPP)
    Neat
  39. Dimethyl phthalate
    0.1 mg/mL in Ethyl acetate
    Single
  40. Didodecyl phthalate
    Neat
  41. Didodecyl phthalate
    100 µg/mL in Methanol
    Single
  42. Diisopropyl phthalate
    Neat
  43. Diisopropyl phthalate
    100 µg/mL in Methanol
    Single
  44. Di-n-heptyl phthalate
    Neat
  45. Di-n-heptyl phthalate
    100 µg/mL in Methanol
    Single
  46. Diundecyl phthalate
    Neat
  47. Diundecyl phthalate
    100 µg/mL in Methanol
    Single
  48. Bis(4-Methylpentyl) phthalate
    Neat
  49. Bis(4-methylpentyl) phthalate
    100 µg/mL in Methanol
    Single
  50. Bis(2-ethylhexyl) cyclohexane-1,2-dicarboxylate
    100 µg/mL in Hexane
    Single
  51. Ethylphthalyl ethyl glycolate
    100 µg/mL in Hexane
    Single

Isophthalates

  1. Dimethyl isophthalate
    Neat
  2. Diphenyl isophthalate
    Neat

Terephthalates

  1. Dimethyl terephthalate
    Neat
  2. Bis(2-ethylhexyl) terephthalate
    Neat
  3. Diethyl terephthalate
    Neat

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Phthalates - Multi-Component Mixes

AccuStandard offers a variety of multi-component mixes of phthalate standards that are designed for different test methods such as AOAC, ISO18856, EPA Method 506, 8060, 8061, and more.

  1. Phthalates in Water-Based Adhesive
    1000 µg/mL in n-Hexane
    9 comps.
  2. Phthalates in Water-Based Adhesive Internal Standard
    100 µg/mL in n-Hexane
    10 comps.
  3. Phthalates in Water-Based Adhesive Internal Standard
    100 µg/mL in n-Hexane
    10 comps.
  4. Appendix IX Phthalate Mix
    1000 µg/mL in Cyclohexane
    6 comps.
  5. Phthalates Mix
    1000 µg/mL in MeOH
    6 comps.
  6. Phthalates Reference Standard
    1000 µg/mL in Ethyl Acetate
    10 comps.
  7. Method 506 - Phthalate Esters
    1000 µg/mL in Isooctane
    7 comps.
  8. Method 506 - Phthalate Esters
    Varied conc. in MeOH
    7 comps.
  9. Phthalate Esters Mix
    0.2 mg/mL in MeOH
    6 comps.
  10. Benzyl benzoate
    5.0 mg/mL in Hexane
    Single
  11. Method 8061 - Phthalate Esters by GC/EC
    1000 µg/mL in Hexane
    15 comps.
  12. Method 8061 - Surrogate Standard Mix
    50 µg/mL in Acetone
    3 comps.
  13. Surrogate Standard
    500 µg/mL in Acetone
    3 comps.
  14. Phthalate Esters
    1000 µg/mL in Hexane
    6 comps.
  15. Matrix Spike Solution
    2.0 mg/mL in Acetone
    2 comps.
  16. Phthalate Esters Mix
    Varied conc. in Acetone
    6 comps.
  17. Adipate and Phthalate Standard
    1000 µg/mL in Acetone
    2 comps.

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Monophthalates

Monophthalate esters are the primary phthalate metabolites formed via hydrolysis of one ester bond. These compounds are thought to be toxic agents; and are receiving interest as a possible human health issue. Studies have shown that they can produce estrogenic and immune-suppressive effects in humans. AccuStandard offers eight monophthalates including the mono-Ethylhexyl (mEHP) which is the metabolite of the plasticizer with the greatest yearly production and use on a global basis.

  1. Monobenzyl phthalate (mBzP)
    Neat
  2. Monobenzyl phthalate (mBzP)
    100 µg/mL in Acetonitrile
    Single
  3. Monobutyl phthalate (mBP)
    Neat
  4. Monobutyl phthalate (mBP)
    100 µg/mL in Acetonitrile
    Single
  5. Monoethyl phthalate (mEP)
    Neat
  6. Monoethyl phthalate (mEP)
    100 µg/mL in Acetonitrile
    Single
  7. Monoethylhexyl phthalate (mEHP)
    Neat
  8. Monoethylhexyl phthalate (mEHP)
    100 µg/mL in Acetonitrile
    Single
  9. Monomethyl phthalate
    Neat
  10. Monomethyl phthalate
    100 µg/mL in Acetonitrile
    Single
  11. Monooctyl phthalate
    Neat
  12. Monooctyl phthalate
    100 µg/mL in Acetonitrile
    Single
  13. Monoisononyl phthalate
    Neat
  14. Monoisononyl phthalate
    100 µg/mL in Acetonitrile
    Single
  15. Mono-2-heptyl phthalate
    Neat
  16. Mono-2-heptyl phthalate
    100 µg/mL in Acetonitrile
    Single
  17. Monohexyl phthalate
    Neat
  18. Monohexyl phthalate
    100 µg/mL in Acetonitrile
    Single
  19. Monoisobutyl phthalate
    Neat
  20. Monoisobutyl phthalate
    100 µg/mL in Acetonitrile
    Single
  21. Mono-n-pentyl phthalate
    Neat
  22. Mono-n-pentyl phthalate
    100 µg/mL in Acetonitrile
    Single
  23. Monocyclohexyl phthalate
    Neat
  24. Monocyclohexyl phthalate
    100 µg/mL in Acetonitrile
    Single
  25. Monoisopropyl phthalate
    Neat
  26. Monoisopropyl phthalate
    100 µg/mL in Acetonitrile
    Single

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Deuterated Phthalates

  1. Dibenzyl phthalate-d4
    100 µg/mL in Methanol
    Single
  2. Di-n-butyl phthalate-d4
    100 µg/mL in Methanol
    Single
  3. Diisobutyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  4. Dicyclohexyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  5. Dicyclohexyl phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  6. Diethyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  7. Di-n-hexyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  8. Di-n-hexyl phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  9. Dimethyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  10. Di-n-octyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  11. Di-n-octyl phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  12. Di-n-pentyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  13. Di-n-propyl phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  14. Bis(2-ethylhexyl) phthalate-3,4,5,6-d4
    100 µg/mL in Methanol
    Single
  15. Bis(2-ethylhexyl) phthalate-d4
    100 µg/mL in n-Hexane
    Single
  16. Bis(2-ethoxyethyl) phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  17. Diphenyl phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  18. Bis(2-butoxyethyl) phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  19. Bis(2-methoxyethyl) phthalate-3,4,5,6-d4
    100 µg/mL in n-Hexane
    Single
  20. Benzyl butyl phthalate-d4
    100 µg/mL in n-Hexane
    Single

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Phthalates - Technical Mixtures

The high molecular weight (HMW) phthalates have more than six carbons in the backbone; and are synthesized from phthalic acid and mixtures of C9 and C10 alcohols. The two major HMW products are diisononyl phthalate (DINP) and diisodecyl phthalate (DIDP). Attention has now turned to the analysis of these compounds as they are becoming major players in the plasticizer marketplace. However, due to the synthesis process, GC separation of DINP and DIDP results in a cluster of peaks corresponding to different isomers. Consequently, different analytical approaches based on soft ionization techniques and MS detection have been documented in the literature (1). These new approaches can provide another tool to scrutinize the amounts, environmental fate and potential health effects of these HMW plasticizers.

  1. Diisodecyl phthalate (Tech Mix)
    Neat
  2. Diisodecyl phthalate (DIDP) (Tech Mix)
    100 µg/mL in MeOH
    Single
  3. Diisononyl phthalate (Tech Mix)
    Neat
  4. Diisononyl phthalate (DINP) (Tech Mix)
    100 µg/mL in MeOH
    Single
  5. Diisooctyl phthalate (Tech Mix)
    Neat
  6. Diisooctyl phthalate (DIOP) (Tech Mix)
    100 µg/mL in Methanol
    Single
  7. Benzyl 2-Ethylhexyl phthalate
    Neat
  8. Benzyl 2-Ethylhexyl phthalate
    100 µg/mL in Methanol
    Single
  9. Butyl octyl phthalate (Tech Mix)
    Neat
  10. Diisohexyl phthalate (Tech Mix)
    Neat
  11. Isobutylcyclohexyl phthalate (Tech Mix)
    Neat
  12. n-Octyl n-decyl phthalate (Tech Mix)
    Neat
  13. Hexyl-2-ethylhexyl phthalate (Tech Mix)
    Neat
  14. Dinonyl phthalate
    Neat
  15. Didecyl phthalate
    Neat
  16. Butyl Cyclohexyl Phthalate (Tech Mix)
    Neat
  17. Decyl octyl phthalate (Tech Mix)
    Neat
  18. Decyl octyl phthalate (Tech Mix)
    100 µg/mL in Methanol
    Single
  19. n-Butyl iso-butyl phthalate (Tech Mix)
    Neat
  20. n-Butyl iso-butyl phthalate (Tech Mix)
    100 µg/mL in Methanol
    Single
  21. n-Butyl benzyl phthalate
    Neat
  22. n-Butyl benzyl phthalate
    100 µg/mL in MeOH
    Single
  23. Iso-butyl benzyl phthalate (Tech Mix)
    Neat
  24. Iso-butyl benzyl phthalate (Tech Mix)
    100 µg/mL in Methanol
    Single
  25. Pentyl Isopentyl phthalate (Tech Mix)
    Neat
  26. Pentyl Isopentyl Phthalate (Tech Mix)
    100 µg/mL in Methanol
    Single
  27. Jayflex® 77
    Neat
  28. Jayflex® 77
    1000 µg/mL in Hexane
    Single

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Phthalate Replacement Standards

Concern over enviromental and health-related factors associated with phthalates has led to restrictions of use in a wide array of products. This has resulted in the plastics industry generating a variety of alternatives. In response, AccuStandard has developed a phthalate replacement product line comprised of 42 compounds representing 18 chemical classes.

Azelaic Acid Derivatives

  1. Diisodecyl azelate
    1000 µg/mL in Acetone
    Single
  2. Diisooctyl azelate
    1000 µg/mL in Acetone
    Single
  3. Dimethyl azelate
    1000 µg/mL in Acetone
    Single
  4. Di-n-hexyl azelate
    1000 µg/mL in Acetone
    Single
  5. Di(2-ethylhexyl) azelate
    1000 µg/mL in Acetone
    Single

Adipic Acid Derivatives

  1. Di(tridecyl) adipate
    1000 µg/mL in Acetone
    Single
  2. Di(n-heptyl, n-nonyl) adipate
    1000 µg/mL in Hexane
    Single
  3. Diisobutyl adipate
    1000 µg/mL in Hexane
    Single
  4. Diisodecyl adipate
    1000 µg/mL in Hexane
    Single

Dimer Acid Derivative

  1. Bis(2-hydroxyethyl) dimerate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  2. Epoxidized linseed oil
    1000 µg/mL in Toluene
    Single
  3. 2-Ethylhexyl epoxy tallate
    1000 µg/mL in Hexane
    Single

Fumeric Acid Derivative

  1. Dibutyl furmarate
    1000 µg/mL in Hexane
    Single

Glycerol Derivative

  1. Glycerol triacetate
    1000 µg/mL in Hexane
    Single

Isobutyrate Derivative

  1. 2,2,4-Trimethyl-1,3-pentanediol-diisobutyrate
    1000 µg/mL in Hexane
    Single

Linoleic Acid Derivatives

  1. bis(2-Ethylhexyl)maleate
    1000 µg/mL in Hexane
    Single
  2. Di-n-butyl maleate
    1000 µg/mL in Hexane
    Single

Mellitates

  1. Tricapryl trimellitate
    1000 µg/mL in Hexane
    Single
  2. Triisodecyl trimellitate
    1000 µg/mL in Hexane
    Single
  3. Tri(n-octyl, n-decyl)trimellitate (Industrial Product)
    1000 µg/mL in Hexane
    Single

Myristate

  1. Isopropyl myristate
    1000 µg/mL in Hexane
    Single
  2. Glycerol monooleate (Industrial Product ~50%)
    1000 µg/mL in Hexane
    Single
  3. Methyl oleate
    1000 µg/mL in Hexane
    Single
  4. n-Propyl oleate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  5. Tetrahydrofurfuryl oleate (Industrial Product)
    1000 µg/mL in Hexane
    Single

Palmitic Acid Derivative

  1. Isopropyl palmitate
    1000 µg/mL in Hexane
    Single

Benzoic Acid Derivatives

  1. Di(propylene glycol) dibenzoate
    1000 µg/mL in Hexane
    Single
  2. Polyethylene glycol 200 dibenzoate
    1000 µg/mL in Hexane
    Single

Phosphoric Acid Derivatives

  1. t-Butylphenyl diphenyl phosphate
    1000 µg/mL in Hexane
    Single
  2. Tri-butoxyethyl phosphate
    1000 µg/mL in Hexane
    Single

Ricinoleic Acid Derivatives

  1. Butyl ricinoleate
    1000 µg/mL in Hexane
    Single
  2. Glyceryl (tri-acetyl) ricinoleate
    1000 µg/mL in Hexane
    Single
  3. n-Butyl acetyl ricinoleate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  4. Propylene glycol ricinoleate (Industrial Product)
    1000 µg/mL in Toluene
    Single

Succinic Acid Derivative

  1. Diethyl succinate
    1000 µg/mL in Hexane
    Single

Sulfonic Acid Derivative

  1. N-Ethyl o/p-toluenesulfonamide (Industrial Product)
    1000 µg/mL in Toluene
    Single

Stearic Acid Derivatives

  1. Ethylene glycol monostearate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  2. Isopropyl isostearate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  3. n-Butyl stearate (Industrial Product)
    1000 µg/mL in Hexane
    Single
  4. Glycerol monostearate
    1000 µg/mL in Toluene
    Single
  5. Propylene glycol monostearate (Industrial Product)
    1000 µg/mL in Hexane
    Single

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